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Supplementary material (ESI) for Journal of Materials Chemistry This journal is ? The Royal Society of Chemistry

2009 Supporting Information Syntheses, structures, and magnetic properties of heterometallic coordination polymers with carboxyphosphonate linkers Zhi-Guo Gu, Slaci C.

Sevov Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana

46556 ssevov@nd.edu Supplementary material (ESI) for Journal of Materials Chemistry This journal is ? The Royal Society of Chemistry

2009 Table S1 Selected bond lengths (?) for 1-CuMn, 2-CuCo, 3-CuCd, 4-CuLa and 5-CuNd 1-CuMn Mn(1)?O(13A) 2.049(2) Mn(1)?O(17) 2.133(2) Mn(1)?O(7) 2.160(2) Mn(1)?O(15) 2.175(3) Mn(1)?O(11B) 2.199(2) Mn(1)?O(16) 2.243(3) Mn(2)?O(6) 2.098(2) Mn(2)?O(12) 2.121(2) Mn(2)?O(21) 2.188(2) Mn(2)?O(18) 2.213(2) Mn(2)?O(20) 2.235(2) Mn(2)?O(19) 2.270(3) Cu(1)?O(14A) 1.894(2) Cu(1)?O(3) 1.965(2) Cu(1)?O(1) 1.978(2) Cu(1)?N(1) 2.021(2) Cu(1)?O(7) 2.281(2) Cu(2)?O(5) 1.914(2) Cu(2)?O(8) 1.940(3) Cu(2)?O(10) 1.960(2) Cu(2)?N(2) 2.015(3) Cu(2)?O(12) 2.317(2) Symmetry codes: A x + 1/2, Cy + 1/2, z C 1/2;

B x + 1, y, z 2-CuCo Co(1)?O(13A) 1.967(3) Co(1)?O(17) 2.012(3) Co(1)?O(7) 2.128(2) Co(1)?O(15) 2.078(3) Co(1)?O(11B) 2.121(3) Co(1)?O(16) 2.202(4) Co(2)?O(6) 2.054(2) Co(2)?O(12) 2.065(2) Co(2)?O(21) 2.086(3) Co(2)?O(18) 2.118(3) Co(2)?O(20) 2.147(3) Co(2)?O(19) 2.146(3) Cu(1)?O(14A) 1.889(3) Cu(1)?O(3) 1.963(3) Cu(1)?O(1) 1.974(3) Cu(1)?N(1) 2.015(3) Cu(1)?O(7) 2.259(2) Cu(2)?O(5) 1.909(2) Cu(2)?O(8) 1.947(3) Cu(2)?O(10) 1.957(3) Cu(2)?N(2) 2.008(3) Cu(2)?O(12) 2.297(2) Symmetry codes: A x + 1/2, Cy + 1/2, z C 1/2;

B x + 1, y, z 3-CuCd Cd(1)?O(13A) 2.105(4) Cd(1)?O(17) 2.164(4) Cd(1)?O(7) 2.242(3) Cd(1)?O(15) 2.252(5) Cd(1)?O(11B) 2.272(4) Cd(1)?O(16) 2.332(5) Cd(2)?O(6) 2.208(3) Cd(2)?O(12) 2.212(4) Cd(2)?O(21) 2.277(4) Cd(2)?O(18) 2.307(4) Cd(2)?O(20) 2.318(4) Cd(2)?O(19) 2.349(4) Cu(1)?O(14A) 1.899(4) Cu(1)?O(3) 1.971(4) Cu(1)?O(1) 1.988(4) Cu(1)?N(1) 2.021(4) Cu(1)?O(7) 2.240(3) Cu(2)?O(5) 1.917(4) Cu(2)?O(8) 1.934(4) Cu(2)?O(10) 1.956(4) Cu(2)?N(2) 2.022(4) Cu(2)?O(12) 2.286(4) Symmetry codes: A x + 1/2, Cy + 1/2, z C 1/2;

B x + 1, y, z 4-CuLa Cu(1)?O(6) 1.934(3) Cu(1)?O(1A) 1.953(3) Cu(1)?O(3A) 1.962(3) Cu(1)?N(1A) 2.019(3) Cu(1)?O(13) 2.637(3) Cu(1)?O(7A) 2.530(3) La(1)?O(5) 2.466(3) La(1)?O(11) 2.532(3) La(1)?O(2B) 2.540(3) La(1)?O(9) 2.557(3) La(1)?O(10) 2.562(3) La(1)?O(8) 2.632(3) La(1)?O(3C) 2.639(3) La(1)?O(4C) 2.765(3) La(1)?O(7A) 2.450(3) Symmetry codes: A x, Cy + 1/2, z + 1/2;

B x C 1, y, z;

C x, y, z +

1 5-CuNd Cu(1)?O(6) 1.927(2) Cu(1)?O(1A) 1.952(2) Cu(1)?O(3A) 1.962(2) Cu(1)?N(1A) 2.004(3) Cu(1)?O(13) 2.613(3) Cu1(1)?O(7A) 2.591(4) Nd(1)?O(5) 2.420(2) Nd(1)?O(11) 2.477(2) Nd(1)?O(2B) 2.483(2) Nd(1)?O(9) 2.508(2) Nd(1)?O(10) 2.506(2) Nd(1)?O(8) 2.566(2) Nd(1)?O(3C) 2.577(2) Nd(1)?O(4C) 2.735(2) Nd(1)?O(7A) 2.384(2) Symmetry codes: A x, Cy + 1/2, z + 1/2;

B x C 1, y, z;

C x, y, z +

1 Supplementary material (ESI) for Journal of Materials Chemistry This journal is ? The Royal Society of Chemistry

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100 % Transmittance Wavenumbers (cm ?1 ) 4-CuLa 5-CuNd Fig. S2 FT-IR spectroscopy for as-synthesized samples of 4-CuLa and 5-CuNd. FT-IR (cm-1 ) data for: 1-CuMn:

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