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高等学校化学学报

2008 29 (1): 60-63 ISSN: 0251-0790 CN: 22-1131/O6 研究论文 扩展功能 本文信息 Supporting info PDF(306KB) [HTML全文](0KB) 参考文献 服务与反馈 把本文推荐给朋友 加入我的书架 加入引用管理器 引用本文 Email Alert 文章反馈 浏览反馈信息 相关信息 本刊中 包含"表面等离子体共振" 的 相关文章 本文作者相关文章 ・ 陈受惠 ・ 倪永年 ・ 杨帆 ・ 杨秀荣 表面等离子体共振技术与循环伏安法联用检测甲苯胺蓝 陈受惠1, 倪永年1, 杨帆2, 杨秀荣2 1.

南昌大学化学系, 南昌 330031;

2. 中国科学院长春应用化学研究所电分析化学国家重点实验室, 长春

130022 收稿日期 2007-4-29 修回日期 网络版发布日期 2008-1-16 接受日期 摘要 将表面等离子体共振技术(SPR) 与循环伏安法(CV) 联用, 并用小波变换提取实验数据, 实现了甲苯胺蓝的 定量检测. 以传感片上的金膜为SPR测量基底, 并作为电化学的工作电极, 以Ag/AgCl电极(饱和KCl) 为参比电极, 以铂丝为对电极, 同时进行SPR扫描和循环伏安法扫描, 发现电化学聚合导致甲苯胺蓝氧化峰峰电位正移, 还原峰 峰电位不变, 而SPR响应也整体下降;

将SPR响应对电位求导后进而对电位作图, 经小波变换处理后, 发现波谱峰 电位接近循环伏安法氧化还原法电位. 利用该方法检测甲苯胺蓝的检出限与采用循环伏安法检测甲苯胺蓝的检出 限在一个数量级上. 关键词 表面等离子体共振 循环伏安法 甲苯胺蓝 小波变换 动力学分析 分类号 O659.31 DOI: Determination of Toluidine Blue by Combination of Surface Plasmon Resonance with Cyclic Voltammetry CHEN Shou-Hui1, NI Yong-Nian1*, YANG Fan2, YANG Xiu-Rong2 1. Department of Chemistry, Nanchang Univesity, Nanchang 330031, China;

2. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China Received 2007-4-29 Revised Online 2008-1-16 Accepted Abstract A method based on the combination of surface plasmon resonance(SPR) with cyclic voltammetry(CV) with the aid of wavelet transform technique was established for the detection of toluidine blue. The gold film of the sensor chip was used as both the generator of SPR measurement and the work electrode of electrochemistry analysis, Ag/AgCl electrode as the reference electrode, and the Pt electrode as the counter electrode. The scans of SPR and CV were performed simultaneously. The results show that due to electro-chemical polymerization of toluidine blue, the potential of oxidation peak shifted positively, the potential of reduction peak remained constant, and the response of SPR fell totally. The results obtained by taking derivative on the SPR response were processed by wavelet transform, and it was found that the response increased linearly with the concentration in range of 8.18―16.35 mmol/L for toluidine blue, with the limit of detection(LOD) of 4.01 mmol/L. Both the linear range and the LOD obtained by the proposed method compare well with the figures of merit given by the CV. Key words Surface plasmon resonance(SPR);

Cyclic voltammetry(CV);

Toluidine blue;

Wavelet transform;

Kinetic analysis 通讯作者: 倪永年 ynni@ncu.edu.cn 作者个人主页: 陈受惠1 ;

倪永年1 ;

杨帆2 ;

杨秀荣2