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1 H, J = 4.8, 1.6 Hz), 7.67 (dd,

1 H, J = 7.6, 1.6 Hz), 7.41-7.45 (m,

5 H), 7.30 (dd,

1 H, J = 7.2, 4.8 Hz). MS (EI): m/z (%):

191 (31) [M+ ] (37 Cl),

189 (100) [M+ ] (35 Cl),

154 (50),

127 (35). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S6

3、 N H2N 5-phenylpyridin-2-amine [T2-3, 33421-40-8, Ref. 3]

1 H NMR (400 MHz, CDCl3, TMS) δ 8.33 (d,

1 H, J = 1.6 Hz), 7.66 (dd,

1 H, J = 8.0, 2.4 Hz), 7.49-7.52 (m,

2 H), 7.40-7.44 (m,

2 H), 7.29-7.33 (m,

1 H), 6.56 (dd,

1 H, J = 8.4, 0.8 Hz), 4.53 (brs,

2 H). MS (EI): m/z (%):

171 (12) [M+ +1],

170 (100) [M+ ],

169 (18) [M+ -1],

143 (24),

115 (21). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S7

4、 N NH2 5-methyl-3-phenylpyridin-2-amine [T2-4, 351001-77-9, Ref. 4]

1 H NMR (400 MHz, CDCl3, TMS) δ 7.87 (s,

1 H), 7.42-7.43 (m,

4 H), 7.33-7.36 (m,

1 H), 7.18-7.19 (d,

1 H, J = 2.0 Hz), 4.56 (brs,

2 H), 2.21 (s,

3 H). MS (EI): m/z (%):

184 (57) [M+ ],

183 (100) [M+ -1],

168 (8). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S8

5、 N 2-Phenyl-pyridine [T2-5, 1008-89-5, Ref. 1,5]

1 H NMR (400 MHz, CDCl3, TMS) δ 8.68-8.69 (m,

1 H), 7.97-7.99 (m,

2 H), 7.69-7.71 (m,

2 H), 7.38-7.48 (m,

3 H), 7.17-7.21 (m,

1 H). MS (EI): m/z (%):

155 (100) [M+ ],

154 (21),

153 (7),

115 (7),

76 (9). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S9

6、 N 2,6-diphenylpyridine [T2-6, 3558-69-8, Ref. 6]

1 H NMR (400 MHz, CDCl3, TMS) δ 8.13-8.15 (m,

4 H), 7.75 (dd,

1 H, J = 8.8, 7.2 Hz), 7.64-7.66 (d,

2 H, J = 7.2 Hz), 7.46-7.50 (m,

4 H), 7.39-7.43 (m,

2 H). MS (EI): m/z (%):

232 (16) [M+ +1],

231 (100) [M+ ],

230 (63) [M+ -1],

102 (11). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S10

7、 N N 5-phenylpyrimidine [T2-7, 34771-45-4, Ref. 7]

1 H NMR (400 MHz, CDCl3, TMS) δ 9.15 (s,

1 H), 8.89 (s,

2 H), 7.41-7.53 (m,

5 H). MS (EI): m/z (%):

157 (10) [M+ +1],

156 (100) [M+ ],

155 (15) [M+ -1],

102 (54). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S11

8、 N 3-phenylquinoline [T2-8, 1666-96-2, Ref. 8]

1 H NMR (400 MHz, CDCl3, TMS) δ 9.18 (d,

1 H, J = 2.0 Hz), 8.22 (d,

1 H, J = 1.6 Hz ), 8.14-8.16 (d,

1 H, J = 8.8 Hz), 7.80-7.82 (d,

1 H, J = 8.4 Hz), 7.65-7.71 (m,

3 H), 7.47-7.55 (m,

3 H), 7.38-7.42 (m,

1 H). MS (EI): m/z (%):

206 (17) [M+ +1],

205 (100) [M+ ],

204 (51) [M+ -1],

176 (13),

151 (8),

102 (10),

88 (11),

76 (15),

44 (14). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S12

9、 N 4-phenylisoquinoline [T2-9, 19571-30-3, Ref. 8]

1 H NMR (400 MHz, CDCl3, TMS) δ 9.26 (s,

1 H), 8.50 (s,

1 H), 8.02-8.04 (d,

1 H, J = 7.6 Hz), 7.91-7.93 (d,

1 H, J = 8.4 Hz), 7.62-7.66 (m,

2 H), 7.47-7.53 (m,

5 H). MS (EI): m/z (%):

206 (16) [M+ +1],

205 (100) [M+ ],

204 (72) [M+ -1],

176 (23),

151 (9),

102 (17),

88 (15),

76 (11). Supplementary Material (ESI) for Green Chemistry This journal is ? The Royal Society of Chemistry

2008 S13

10、 N H 5-phenyl-1H-indole [T2-10, 66616-72-6, Ref. 9]

1 H NMR (400 MHz, CDCl3, TMS) δ 8.21 (s,